Solvent effects on the amidic bond. 1H nuclear magnetic resonance study of acetamide and N-methylacetamide
Author
dc.contributor.author
Gonzalez, Guillermo
Author
dc.contributor.author
Chavez, Ivonne
Admission date
dc.date.accessioned
2018-12-20T14:05:53Z
Available date
dc.date.available
2018-12-20T14:05:53Z
Publication date
dc.date.issued
1981
Cita de ítem
dc.identifier.citation
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, Volumen 77, Issue 12, 2018, Pages 2231-2236
Identifier
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03009238
Identifier
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10.1039/F29817702231
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/153800
Abstract
dc.description.abstract
The influence of various common basic solvents on the 1H n.m.r. spectra of the N-H protons in N-methylacetamide and acetamide has been studied. The chemical shifts at infinite dilution show approximately linear relationships with the donor number of the solvent. In strong donor solvents it is possible to observe the n.m.r. signals of two non-equivalent amidic protons in acetamide owing to the effect of the solvent on C-N rotation. The influence of the solvent on the chemical shifts and line splittings is discussed as well as the concentration effects by considering possible solute-solvent and solute-solute interactions.