Electron localization function as a measure of electron delocalization and aromaticity
Author
dc.contributor.author
Fuentealba Rosas, Patricio
Author
dc.contributor.author
Santos, Juan C.
Admission date
dc.date.accessioned
2018-12-20T14:06:15Z
Available date
dc.date.available
2018-12-20T14:06:15Z
Publication date
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2011
Cita de ítem
dc.identifier.citation
Current Organic Chemistry, Volumen 15, Issue 20, 2018, Pages 3619-3626
Identifier
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13852728
Identifier
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10.2174/138527211797636200
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/153874
Abstract
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The Electron Localization Function (ELF) has played in the last time an important role in understanding the special characteristics of the chemical bond. The chemical interpretation of the ELF as an indicator of the regions of the space where it is most probable to find a localized electron pair has been of great value in order to understand some complex chemical bonds. In this work, the ELF has been used to study the delocalization and aromatic character of a diversity of molecules. It is shown that whereas the analysis of the total ELF does not provide clear information about aromaticity, the separation of the function on its σ and π parts yields indeed valuable information about it. Moreover, it is possible to construct a quantitative scale of aromaticity. It is also shown that the use of the ELF to understand aromaticity is complementary to other methodologies. The study includes mono substituted benzene derivatives, cyclic organic compounds, borazine molecule and the mechanism of