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Oxidation of mesoionic oxazolones by oxygen

Authordc.contributor.authorRodriguez, H. 
Authordc.contributor.authorMarquez, A. 
Authordc.contributor.authorChuaqui, C. A. 
Authordc.contributor.authorGomez, B. 
Admission datedc.date.accessioned2018-12-20T14:06:20Z
Available datedc.date.available2018-12-20T14:06:20Z
Publication datedc.date.issued1991
Cita de ítemdc.identifier.citationTetrahedron, Volumen 47, Issue 30, 2018, Pages 5681-5688
Identifierdc.identifier.issn00404020
Identifierdc.identifier.other10.1016/S0040-4020(01)86521-2
Identifierdc.identifier.urihttps://repositorio.uchile.cl/handle/2250/153912
Abstractdc.description.abstractThe reaction of molecular oxygen with several 2,4-disubstituted oxazolones (3a-3g) is studied in the present paper. It is shown that oxygen may induce oxidative dimerization to dehydrodimers (7a-7g) via the mesoionic form of the oxazolone. The equilibriation between the ketonic and the mesoionic forms. It is demonstrated that this equilibrium and the dimerization process are dependent on the properties of the solvent and the type of substitution in the oxazolones. © 1991.
Lenguagedc.language.isoen
Type of licensedc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
Link to Licensedc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
Sourcedc.sourceTetrahedron
Keywordsdc.subjectBiochemistry
Keywordsdc.subjectDrug Discovery
Keywordsdc.subjectOrganic Chemistry
Títulodc.titleOxidation of mesoionic oxazolones by oxygen
Document typedc.typeArtículo de revista
Catalogueruchile.catalogadorSCOPUS
Indexationuchile.indexArtículo de publicación SCOPUS
uchile.cosechauchile.cosechaSI


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