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Author | dc.contributor.author | Domingo, Luis R. | |
Author | dc.contributor.author | Pérez, Patricia | |
Author | dc.contributor.author | Contreras Ramos, Renato | |
Admission date | dc.date.accessioned | 2018-12-20T14:11:15Z | |
Available date | dc.date.available | 2018-12-20T14:11:15Z | |
Publication date | dc.date.issued | 2006 | |
Identifier | dc.identifier.issn | 1434193X | |
Identifier | dc.identifier.other | 10.1002/ejoc.200500466 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/154524 | |
Abstract | dc.description.abstract | Small cycloalkynes possess a π-strain-induced electrophilicity related to the bending of the Csp3-Csp-Csp bond angle. For cyclopentyne and benzyne, the electrophilicity index defined in the context of density functional theory gives a coherent rationale for the reactivity of these cycloalkynes, which may act as electrophiles in polar cycloaddition reactions toward enol ethers. © Wiley-VCH Verlag GmbH & Co. KGaA, 2006. | |
Lenguage | dc.language.iso | en | |
Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
Source | dc.source | European Journal of Organic Chemistry | |
Keywords | dc.subject | Cycloadditions | |
Keywords | dc.subject | Cycloalkynes | |
Keywords | dc.subject | Density functional calculations | |
Keywords | dc.subject | Electrophilicity | |
Keywords | dc.subject | Strain | |
Título | dc.title | π-strain-induced electrophilicity in small cycloalkynes: A DFT analysis of the polar cycloaddition of cyclopentyne towards enol ethers | |
Document type | dc.type | Artículo de revista | |
Cataloguer | uchile.catalogador | SCOPUS | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |
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