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Author | dc.contributor.author | Gómez Jeria, Juan | |
Author | dc.contributor.author | Morales Lagos, Demian | |
Admission date | dc.date.accessioned | 2018-12-20T14:11:20Z | |
Available date | dc.date.available | 2018-12-20T14:11:20Z | |
Publication date | dc.date.issued | 1990 | |
Cita de ítem | dc.identifier.citation | Journal of Physical Chemistry, Volumen 94, Issue 9, 2018, Pages 3790-3795 | |
Identifier | dc.identifier.issn | 00223654 | |
Identifier | dc.identifier.other | 10.1021/j100372a081 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/154562 | |
Abstract | dc.description.abstract | We present a theoretical treatment for the Helmholtz free energy of an arbitrary discrete charge distribution in a central prolate or oblate spheroidal cavity surrounded by two and three concentric dielectric continua of the same symmetry. The electrostatic interaction is accounted for by a multipolar expansion. This model permits us to consider in a simple way nonlinear dielectric effects and the nonsphericity of solute molecules. The results are presented in a suitable form to discuss them in terms of a virtual polarization charge distribution. Also, we give an explicit expression for the contributions coming from the zeroth-order multipole moments for any number of shells. © 1990 American Chemical Society. | |
Lenguage | dc.language.iso | en | |
Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
Source | dc.source | Journal of Physical Chemistry | |
Keywords | dc.subject | Engineering (all) | |
Keywords | dc.subject | Physical and Theoretical Chemistry | |
Título | dc.title | Free energy of a charge distribution in a spheroidal cavity surrounded by concentric dielectric continua | |
Document type | dc.type | Artículo de revista | |
Cataloguer | uchile.catalogador | SCOPUS | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |
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