Sulphurating and coordinating properties of N,N′-thiobismorpholine towards iron carbonyls
| Author | dc.contributor.author | Diaz, Carlos | |
| Admission date | dc.date.accessioned | 2018-12-20T14:11:49Z | |
| Available date | dc.date.available | 2018-12-20T14:11:49Z | |
| Publication date | dc.date.issued | 1990 | |
| Cita de ítem | dc.identifier.citation | Polyhedron, Volumen 9, Issue 8, 2018, Pages 1045-1049 | |
| Identifier | dc.identifier.issn | 02775387 | |
| Identifier | dc.identifier.other | 10.1016/S0277-5387(00)81292-9 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/154664 | |
| Abstract | dc.description.abstract | The reactions of N,N′-thiobismorpholine, {A figure is presented}, with Fe(CO)5, Fe2(CO)9, Fe3(CO)11 and [(η5-C5H5)Fe(CO)2THF]BF4 were examined. Thiobismorpholine undergoes desulphurization towards Fe(CO)5 with formation of Fe3(CO)9S2, while the novel complex Fe(CO)4{A figure is presented} was isolated and characterized from the reaction with Fe2(CO)9. On the other hand, thiobismorpholine is somewhat unreactive towards Fe3(CO)11 but it undergoes SN fission with [(η5-C5H5)Fe(CO)2THF]BF4. © 1990. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Polyhedron | |
| Keywords | dc.subject | Physical and Theoretical Chemistry | |
| Keywords | dc.subject | Inorganic Chemistry | |
| Keywords | dc.subject | Materials Chemistry | |
| Título | dc.title | Sulphurating and coordinating properties of N,N′-thiobismorpholine towards iron carbonyls | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile