The crystal structure of a novel sulfenamide: (N,N-dibenzyl)bencenesulfenamide
Author
dc.contributor.author
Brito, Ivan
Author
dc.contributor.author
Díaz, Carlos
Author
dc.contributor.author
González Moraga, Guillermo
Author
dc.contributor.author
Rodriguez, Matias Lopez
Author
dc.contributor.author
Manriquez, V.
Admission date
dc.date.accessioned
2018-12-20T14:26:56Z
Available date
dc.date.available
2018-12-20T14:26:56Z
Publication date
dc.date.issued
1999
Cita de ítem
dc.identifier.citation
Boletin de la Sociedad Chilena de Quimica, Volumen 44, Issue 4, 2018, Pages 459-462
Identifier
dc.identifier.issn
03661644
Identifier
dc.identifier.other
10.4067/S0366-16441999000400009
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/156056
Abstract
dc.description.abstract
The crystal structure of (N,N-dibenzyl)bencenesulfenamide, (C6H5)SN(CH2C6H5) 2 is described and compared with other sulfenamides and with its chromium pentacarbonyl complex. This structure belongs to a type of divalent sulphur compound and crystallized in the triclinic system, space group P ⊥ with a = 5.552(3), b = 11.527(4), c = 13.670(8) Å, α = 79.30(4), β= 89.90(4), ρ = 89.70(3)° and Dx = 1.284 g cm-3 with Z=2. The N-S distance is 1.681 (10) Å, which is significantly shorter than the reported for its chromium pentacarbonyl complex and than a single S-N bond [1.74 Å].