An evidence of mixed-valence electron transfer in the inverted Marcus region
| Author | dc.contributor.author | Diaz, Carlos | |
| Author | dc.contributor.author | Arancibia, Alejandra | |
| Admission date | dc.date.accessioned | 2018-12-20T14:35:53Z | |
| Available date | dc.date.available | 2018-12-20T14:35:53Z | |
| Publication date | dc.date.issued | 1998 | |
| Cita de ítem | dc.identifier.citation | Boletin de la Sociedad Chilena de Quimica, Volumen 43, Issue 1, 2018, Pages 097-102 | |
| Identifier | dc.identifier.issn | 03661644 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/156611 | |
| Abstract | dc.description.abstract | The rates electron transfer ket for the mixed-valence complexes [Cd(dppe)Fe-CN-MLn]+2, MLn = Cp(dppe)Fe, Mn(CO)2dppmP(OPh)3 and other cyanide bridged complexes were estimated from the intervalence transition parameters. The ket values correlate inversely with the free-energy driving force (-ΔG°) estimated from the half-wave potentials. The results can be interpreted as an evidence of the inverted region of Marcus in mixed-valence complexes. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Boletin de la Sociedad Chilena de Quimica | |
| Keywords | dc.subject | Electron transfer | |
| Keywords | dc.subject | Inverted region | |
| Keywords | dc.subject | Iron-cyanide complexes | |
| Keywords | dc.subject | Marcus theory | |
| Keywords | dc.subject | Mixed-valence | |
| Título | dc.title | An evidence of mixed-valence electron transfer in the inverted Marcus region | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivs 3.0 Chile