Complexes of bivalent cations with neryl and geranyl pyrophosphate: Their role in terpene biosynthesis
| Author | dc.contributor.author | Chayet, Liliana | |
| Author | dc.contributor.author | Rojas, M. Cecilia | |
| Author | dc.contributor.author | Cori, Osvaldo | |
| Author | dc.contributor.author | Bunton, Clifford A. | |
| Author | dc.contributor.author | McKenzie, Don C. | |
| Admission date | dc.date.accessioned | 2018-12-20T14:37:55Z | |
| Available date | dc.date.available | 2018-12-20T14:37:55Z | |
| Publication date | dc.date.issued | 1984 | |
| Cita de ítem | dc.identifier.citation | Bioorganic Chemistry, Volumen 12, Issue 4, 2018, Pages 329-338 | |
| Identifier | dc.identifier.issn | 10902120 | |
| Identifier | dc.identifier.issn | 00452068 | |
| Identifier | dc.identifier.other | 10.1016/0045-2068(84)90014-2 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/156742 | |
| Abstract | dc.description.abstract | Kinetic analysis of the nonenzymic solvolysis of neryl and geranyl pyrophosphate (NPP and GPP, respectively) showed that the dissociation constants of the bis-metallic complexes with Mg2+ and Mn2+ were larger for NPP than for GPP by approximately one order of magnitude. Rate constants for reaction of the bis-metallic complexes were larger for NPP than for GPP. Qualitatively similar behavior was observed with complexes of Co2+. Extents of elimination and cyclization were increased by metal ions. Carbocyclase-catalyzed formation of cyclic monoterpene hydrocarbons in the presence of Mg2+ involved bis-metallic complexes as the "true" substrates. © 1984. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Bioorganic Chemistry | |
| Keywords | dc.subject | Biochemistry | |
| Keywords | dc.subject | Molecular Biology | |
| Keywords | dc.subject | Drug Discovery | |
| Keywords | dc.subject | Organic Chemistry | |
| Título | dc.title | Complexes of bivalent cations with neryl and geranyl pyrophosphate: Their role in terpene biosynthesis | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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