New coordination mode of bis(diphenylphosphine) methanide diselenide. Synthesis and X-ray crystal structure of [(η5 C5Me5)Rh&{η3 (SePPh2)2CH&}]ClO4
| Author | dc.contributor.author | Valderrama, Mauricio | |
| Author | dc.contributor.author | Contreras, Raul | |
| Author | dc.contributor.author | Bascuñan, Manuel | |
| Author | dc.contributor.author | Boys, Daphne | |
| Admission date | dc.date.accessioned | 2018-12-20T14:39:22Z | |
| Available date | dc.date.available | 2018-12-20T14:39:22Z | |
| Publication date | dc.date.issued | 1994 | |
| Cita de ítem | dc.identifier.citation | Polyhedron, Volumen 13, Issue 6-7, 2018, Pages 1101-1103 | |
| Identifier | dc.identifier.issn | 02775387 | |
| Identifier | dc.identifier.other | 10.1016/S0277-5387(00)83041-7 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/156886 | |
| Abstract | dc.description.abstract | The dinuclear complexes [(η5 C5Me5)RhCl2]2 and [(η6 C6Me6)RuCl2]2 reacted with dppmSe2 giving the cationic compounds [(η5 C5Me5)RhCl&{η2 (SePPh2)2CH2&}]+ (1) and [(η6 C6Me6)RuCl&{η2 (SePPh2)2CH2&}]+ (2), which were isolated as perchlorate salts. Deprotonation reactions of these compounds yielded the new complexes [(η5 C5Me5)Rh&{η3 (SePPh2)2CH&}]ClO4 (3) and [(η6 C6Me6)Ru&{η3 (SePPh2)2CH&}]ClO4 (4), respectively, in which the anionic methanide diselenide ligand is acting as a tripod ligand, with a C,Se,Se′-donor set. The structure of 3 has been determined by X-ray crystallography. © 1994. | |
| Lenguage | dc.language.iso | en | |
| Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
| Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
| Source | dc.source | Polyhedron | |
| Keywords | dc.subject | Biochemistry | |
| Keywords | dc.subject | Inorganic Chemistry | |
| Keywords | dc.subject | Physical and Theoretical Chemistry | |
| Keywords | dc.subject | Materials Chemistry | |
| Título | dc.title | New coordination mode of bis(diphenylphosphine) methanide diselenide. Synthesis and X-ray crystal structure of [(η5 C5Me5)Rh&{η3 (SePPh2)2CH&}]ClO4 | |
| Document type | dc.type | Artículo de revista | |
| Cataloguer | uchile.catalogador | SCOPUS | |
| Indexation | uchile.index | Artículo de publicación SCOPUS | |
| uchile.cosecha | uchile.cosecha | SI |
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