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Author | dc.contributor.author | Freire, Eleonora | |
Author | dc.contributor.author | Baggio, Sergio | |
Author | dc.contributor.author | Baggio, Ricardo | |
Author | dc.contributor.author | Garland, María Teresa | |
Admission date | dc.date.accessioned | 2018-12-20T14:39:28Z | |
Available date | dc.date.available | 2018-12-20T14:39:28Z | |
Publication date | dc.date.issued | 1998 | |
Cita de ítem | dc.identifier.citation | Acta Crystallographica Section C: Crystal Structure Communications, Volumen 54, Issue 4, 2018, Pages 464-468 | |
Identifier | dc.identifier.issn | 01082701 | |
Identifier | dc.identifier.other | 10.1107/S0108270197016284 | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/156929 | |
Abstract | dc.description.abstract | © 1998 International Union of Crystallography The structures of [Cu(C12H8N2)2(S4O 6)], (I), and [Cu(C12H8N2)3](S4O 6).5H2O, (II), are reported. Compound (I) consists of infinite polymeric chains where copper displays a typical (4+2) coordination and S4O6 connects Cu(phen)2 (phen is phenanthroline) units through rather long Cu⋯O contacts. Compound (II), instead, has a purely ionic character displaying [Cu(phen)3]2+ and S4O6 2- monomeric units. Equatorial and apical bonds in the copper coordination spheres have mean values of 2.003 (5)/2.467 (12) and 2.056 (3)/2.311 (13) Å for (I) and (II), respectively. Some short O⋯OW contacts in (II) suggest the existence of hydrogen bonding involving some of the water molecules of hydration. | |
Lenguage | dc.language.iso | en | |
Publisher | dc.publisher | Blackwell Munksgaard | |
Type of license | dc.rights | Attribution-NonCommercial-NoDerivs 3.0 Chile | |
Link to License | dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/cl/ | |
Source | dc.source | Acta Crystallographica Section C: Crystal Structure Communications | |
Keywords | dc.subject | Biochemistry, Genetics and Molecular Biology (all) | |
Título | dc.title | Bis(1,10-phenanthroline-N,N′)copper(II) tetrathionate and tris(1,10-phenanthroline-N,N′)copper(II) tetrathionate pentahydrate | |
Document type | dc.type | Artículo de revista | |
Cataloguer | uchile.catalogador | SCOPUS | |
Indexation | uchile.index | Artículo de publicación SCOPUS | |
uchile.cosecha | uchile.cosecha | SI | |
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