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VCD determination of the absolute configuration of stypotriol

Authordc.contributor.authorMuñoz, Marcelo A. 
Authordc.contributor.authorAreche Medina, Carlos 
Authordc.contributor.authorSan Martín Barrientos, Aurelio 
Authordc.contributor.authorRovirosa, Juana 
Authordc.contributor.authorJoseph-Nathan, Pedro 
Admission datedc.date.accessioned2018-12-20T14:41:27Z
Available datedc.date.available2018-12-20T14:41:27Z
Publication datedc.date.issued2009
Cita de ítemdc.identifier.citationNatural Product Communications Vol. 4 (8) 2009
Identifierdc.identifier.issn1934578X
Identifierdc.identifier.issn15559475
Identifierdc.identifier.urihttps://repositorio.uchile.cl/handle/2250/157097
Abstractdc.description.abstractThe absolute configuration of the pentacyclic ichthyotoxin stypotriol, a constituent of Stypopodium zonale, was deduced to be 3S,5R,8R,9R,10S,13S,14S-(-) -1 by vibrational circular dichroism spectroscopy of the derived triacetate 2 in comparison to DFT B3LYP/DGDZVP calculations. Compound 2, C33H46O7 having 300 electrons, is the largest natural product successfully studied by VCD to date.
Lenguagedc.language.isoen
Type of licensedc.rightsAttribution-NonCommercial-NoDerivs 3.0 Chile
Link to Licensedc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
Sourcedc.sourceNatural Product Communications
Keywordsdc.subjectAbsolute configuration
Keywordsdc.subjectStypotriol
Keywordsdc.subjectVCD
Títulodc.titleVCD determination of the absolute configuration of stypotriol
Document typedc.typeArtículo de revista
Catalogueruchile.catalogadorSCOPUS
Indexationuchile.indexArtículo de publicación SCOPUS
uchile.cosechauchile.cosechaSI


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