Water-gas shift reaction catalyzed by mononuclear ruthenium complexes containing bipyridine and phenanthroline derivatives
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Water-gas shift reaction catalyzed by mononuclear ruthenium complexes containing bipyridine and phenanthroline derivatives
Abstract
Ruthenium complexes of the type [RuL(CO)2Cl2], [RuL2Cl2], [RuL2(CO)(H2O)](PF6)2, [RuL2Cl]2(PF6)2, [RuL2(CO)Cl](PF6), and [RuL2(CO3)]·3H2O (where L is a bipyridine or phenanthroline derivative) dissolved in aqueous 2-ethoxyethanol, and in a basic medium of KOH, triethylamine, or trimethylamine, catalyze the water-gas shift reaction under mild conditions (PCO = 0.9 atm at 100°C). Copyright © 2002 John Wiley & Sons, Ltd.
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URI: https://repositorio.uchile.cl/handle/2250/157459
DOI: 10.1002/aoc.353
ISSN: 02682605
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Applied Organometallic Chemistry, Volumen 16, Issue 10, 2018, Pages 597-600
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