Reactivity of chromium(III) and cobalt(III) acetylacetonato complexes
Author
dc.contributor.author
Schirado, T.
Author
dc.contributor.author
Gennari, E.
Author
dc.contributor.author
Merello, R.
Author
dc.contributor.author
Decinti, A.
Author
dc.contributor.author
Bunel Torrealba, Sergio
Admission date
dc.date.accessioned
2018-12-20T15:05:05Z
Available date
dc.date.available
2018-12-20T15:05:05Z
Publication date
dc.date.issued
1971
Cita de ítem
dc.identifier.citation
Journal of Inorganic and Nuclear Chemistry, Volumen 33, Issue 10, 1971, Pages 3417-3426
Identifier
dc.identifier.issn
00221902
Identifier
dc.identifier.other
10.1016/0022-1902(71)80664-4
Identifier
dc.identifier.uri
https://repositorio.uchile.cl/handle/2250/157659
Abstract
dc.description.abstract
A comparative study of the ligand reactivity at the 3-position in trisacetylacetonates of Cr(III) and Co(III), by means of nitration and Vilsmeier-Haack reactions, was attempted. The sequence Co > Cr in both reactions was found. Hückel calculations of reactivity indices were performed and theoretical reactivity results agreed with experiment.