Reactivity of chromium(III) and cobalt(III) acetylacetonato complexes
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Schirado, T.
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Reactivity of chromium(III) and cobalt(III) acetylacetonato complexes
Abstract
A comparative study of the ligand reactivity at the 3-position in trisacetylacetonates of Cr(III) and Co(III), by means of nitration and Vilsmeier-Haack reactions, was attempted. The sequence Co > Cr in both reactions was found. Hückel calculations of reactivity indices were performed and theoretical reactivity results agreed with experiment.
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URI: https://repositorio.uchile.cl/handle/2250/157659
DOI: 10.1016/0022-1902(71)80664-4
ISSN: 00221902
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Journal of Inorganic and Nuclear Chemistry, Volumen 33, Issue 10, 1971, Pages 3417-3426
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