Metal tetrazole complexes: bis-(5-aminotetrazolato)-copper (II)
Access noteAcceso a solo metadatos
MetadataShow full item record
Two crystalline forms of bis-(5-aminotetrazolato)-copper (II) have been prepared and characterized. Visible and ultraviolet spectra of aqueous copper (II)-5-aminotetrazole solution have been examined. Continuous variation experiments reveal 1:2 interactions and a formation constant for the complex in solution has been determined and is about 1012. Infrared studies suggest coördination involves the ring and not the 5-amino group. Acids decompose the complexes and bring about rupture of the tetrazole ring, while decomposition by ammonia does not affect the ring.
Artículo de publicación SCOPUS
Quote ItemJournal of the American Chemical Society, Volumen 82, Issue 1, 1960, Pages 82-85