Browsing by Author "Venegas Yazigi, Diego"
Now showing items 21-36 of 36
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Castillo, C.; Seguin, K.; Aguirre Álvarez, Pedro; Venegas Yazigi, Diego; Viegas, A. D. C.; Spodine Spiridonova, Evgenia; Paredes García, Verónica (Royal Soc Chemistry, 2015)In this study, we are reporting the synthesis and characterization of nanocomposites obtained from the direct reduction of nickel(II) salts on matrices of polyethylene (Pe) and chitosan (Ch) in the presence of serine ...
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Le Fur, Eric; Pivan, J. Y.; Ushak, S.; Venegas Yazigi, Diego; Spodine Spiridonova, Evgenia (Elsevier, 2008)New hybrid organic/inorganic copper oxovanadium compounds of composition [Cu(dpa)(2)](4)V4O12 (1), Cu-2(bipy)(2)V4O12 (2), and Cu-2(bipy)(2)V6O17 (3), which crystallize in the monoclinic 1, 2 and triclinic 3 symmetry, ...
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Ushak, S.; Spodine Spiridonova, Evgenia; Venegas Yazigi, Diego; Le Fur, E.; Pivan, J. Y.; Peña, O.; Cardoso-Gil, R.; Kniep, R. (Royal Society of Chemistry, 2005)The new hybrid organic-inorganic copper oxovanadium phosphates of composition Cu4(bipy)4V4O11(PO 4)2·nH2O (n ∼ 5) (1) and Cu 2(bipy)2V2P2O12 (2) (bipy = 2, 2′-bipyridine) adopting the triclinic symmetry were obtained by ...
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Paredes García, Verónica; Venegas Yazigi, Diego; Cabrera, A.; Valencia Gálvez, P.; Arriagada, M.; Ruiz León, Domingo; Zanocco Loyola, Antonio; Spodine Spiridonova, Evgenia (2009)In this work, we present the synthesis and optical study of the binuclear zinc(II) macrocyclic complexes, derived from 4-methyl-2,6-diformylphenol and 1,2-diaminobenzene (H2L). Two zinc macrocyclic complexes with different ...
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Venegas Yazigi, Diego; Cubillos, M.; Le Fur, E.; Pivan, J. Y.; Garland, María Teresa; Baggio, Ricardo; Spodine Spiridonova, Evgenia (2005)A novel molecular tetrameric zinc cluster with phosphate bridges has been synthesized by a hydrothermal method and characterized by X-ray diffraction. The structure is stabilized by neutral H 3PO 4 and water molecules. ...
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Ushak, S.; Spodine Spiridonova, Evgenia; Venegas Yazigi, Diego; Le Fur, Eric; Pivan, J. Y. (ELSEVIER, 2006-09-08)The hybrid organic/inorganic copper oxovanadium diphosphonates of formula [Cu(bipy)(VO2)(2)(O3PCH2PO3)H2O] 1, which crystallizes in the orthorhombic symmetry, and [Cu(bipy)(VO2)(O3P(CH2)(2)PO2OH)] (.) 1.5H(2)O 2, which ...
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Polyoxometalate cluster [V12B18O60H6] functionalized with the copper(II) bis-ethylenediamine complex Brown, Kareen; Car, Pierre Emmanuel; Vega, Andrés; Venegas Yazigi, Diego; Paredes García, Verónica; Vaz, María G.F.; Allao, Rafael A.; Pivan, Jean-Yves; Le Fur, Eric; Spodine Spiridonova, Evgenia (Elsevier, 2011)Three compounds based on the polyoxometalate building block [V12B18O60H6], (Na)10[(H2O)V12- B18O60H6] 18H2O (1), Na8[Cu(en)2]2[V12B18O60H6](NO3)2 14.7H2O (2), Na7[Cu(en)2]2[V12B18O60H6] (NO3) 15.5H2O (3), (en = ...
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Aravena Ponce, Daniel Alejandro (Universidad de ChileCyberDocs, 2009)A partir de potenciales de óxido-reducción experimentales publicados en literatura para complejos de cobre del tipo: [Cu(L1n)(MeCN)]+ y [Cu(L2R)(Cl)]+, en los que L1n corresponde a ligantes tripodales de fórmula ...
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Cañón Mancisidor, Walter Alberto; Gómez García, Carlos J.; Mínguez Espallargas, Guillermo; Vega, Andrés; Spodine Spiridonova, Evgenia; Venegas Yazigi, Diego; Coronado, Eugenio (The Royal Society of Chemistry, 2014)The addition of water to a chloroform solution of the Cu6 trigonal prism complex [Cu6(U6F)(U2OH)(U3OCH3)2(U2OCH3)2(3,5-Me2pz)6] (1) (3,5-Me2pz- = 3,5-dimethylpyrazolate) results in the formation of the Cu6 planar hexagonal ...
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Moraga Cruz, Carlos; Spodine Spiridonova, Evgenia; Audebrand, Nathalie; Venegas Yazigi, Diego; Paredes García, Verónica (American Chemical Society, 2018)In the present work, we report the synthesis and characterization of two new heterometallic coordination polymers based on Ce-III and containing Co-II or Cu-II cations, assembled by the bifunctional ligand 1H-imidazole-4 ...
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Cancino, Patricio; Spodine Spiridonova, Evgenia; Paredes García, Verónica; Venegas Yazigi, Diego; Vega, Andrés (2013)In the structure of the title compound, {[Cu-2(C10H2O8)-(H2O)(6)]center dot 4H(2)O}(n), the benzene-1,2,4,5-tetracarboxylate ligand, (btec)(4-), is located on a crystallographic inversion centre in a 4-coordination mode. ...
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Cañon Mancisidor, Walter; Spodine Spiridonova, Evgenia; Paredes García, Verónica; Venegas Yazigi, Diego (Springer, 2013)A theoretical study of the magnetic properties, using density functional theory, of a family of trinuclear μ3-OH copper(II) complexes reported in the literature is presented. The reported X-ray crystal structures ...
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Venegas Yazigi, Diego; Cano, Joan; Ruiz, Eliseo; Alvarez, Santiago (ELSEVIER, 2006-10-01)Density functional theory (DFT) calculations on the tetranuclear Ni(II) complex [Ni-4(C5H11O3)(4) (CH3CN)(4)](NO3)(4)center dot 1.33NaNO(3), have been made in order to explain the exchange magnetic phenomenon. Two ferromagnetic ...
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Venegas Yazigi, Diego; Ruiz, Eliseo; Cano, Joan; Alvarez, Santiago (2006)The exchange interactions in a Ni12 complex have been studied by using theoretical methods based on density functional theory. The calculated J values reproduce correctly the S = 12 ground state of this system found ...
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Ushak, Svetlana; Spodine Spiridonova, Evgenia; Le Fur, Eric; Venegas Yazigi, Diego; Pivan, Jean Yves; Schnelle, Walter; Cardoso-Gil, Raul; Kniep, Rüdiger (2006)Full title: Two new hybrid organic/inorganic copper(II)-oxovanadate(V) diphosphonates: [Cu2(phen)2(O3PCH2PO 3)(V2O5)(H2O)]·H 2O and [Cu2(phen)2(O3P(CH 2)3PO3)(V2O5)] ·C3H8. Synthesis, structure, and magnetic properties. ...
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Paredes García, Verónica; Santana, Ricardo C.; Madrid, Rosa; Vega, Andrés; Spodine Spiridonova, Evgenia; Venegas Yazigi, Diego (American Chemical Society, 2013)An unusual and unique conformation of a paddle wheel type binuclear copper(II) complex containing acetate and acetamido ligands, {Cu2(μ2-O2CCH3)4}(OCNH2CH3) (1), was obtained by solvothermal synthesis. The structural ...