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Homofugality: A new reactivity index describing the leaving group ability in homolytic substitution reactions

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2006-06-24
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Guerra, Doris
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Homofugality: A new reactivity index describing the leaving group ability in homolytic substitution reactions
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Author
  • Guerra, Doris;
  • Castillo, Raquel;
  • Andrés, Juan;
  • Fuentealba Rosas, Patricio;
  • Aizman, Arie;
  • Contreras Ramos, Renato;
Abstract
We propose and test a new reactivity index tentatively called homofugality, to quantitatively rank the leaving group ability of radical fragments present in homolytic substitution reactions. The model is validated for a series of S(H)2 processes involving organometallic systems.
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URI: https://repositorio.uchile.cl/handle/2250/118803
ISSN: 0009-2614
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CHEMICAL PHYSICS LETTERS Volume: 424 Issue: 4-6 Pages: 437-442 Published: JUN 24 2006
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