Author | dc.contributor.author | Ormazábal Toledo, Rodrigo | |
Author | dc.contributor.author | Campodónico, Paola R. | es_CL |
Author | dc.contributor.author | Contreras Ramos, Renato | es_CL |
Admission date | dc.date.accessioned | 2011-11-29T13:47:55Z | |
Available date | dc.date.available | 2011-11-29T13:47:55Z | |
Publication date | dc.date.issued | 2011-02-18 | |
Cita de ítem | dc.identifier.citation | Organic Letters Volume: 13 Issue: 4 Pages: 822-824 Published: FEB 18 2011 | es_CL |
Identifier | dc.identifier.issn | 1523-7060 | |
Identifier | dc.identifier.other | DOI: 10.1021/ol103033j | |
Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119373 | |
General note | dc.description | Artículo de publicación ISI | es_CL |
Abstract | dc.description.abstract | It is proposed that the electrofugality of a fragment within a molecule is determined by its group nucleophilicity. The variation of electrofugality should be tightly related to the electron releasing ability of the substituent attached to the electrofuge moiety. This contribution closes the set of relationships between philicity and fugality quantities: while nucleofugality appears related to the group electrophilicity of the leaving group, electrofugality is related to the group nucleophilicity of the permanent group. | es_CL |
Patrocinador | dc.description.sponsorship | Fondecyt 1070715
1100492 | es_CL |
Lenguage | dc.language.iso | en | es_CL |
Publisher | dc.publisher | Amer Chemical Soc | es_CL |
Keywords | dc.subject | Nucleophilic-Substitution Reactions | es_CL |
Título | dc.title | Are Electrophilicity and Electrofugality Related Concepts? A Density Functional Theory Study | es_CL |
Document type | dc.type | Artículo de revista | |