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Are Electrophilicity and Electrofugality Related Concepts? A Density Functional Theory Study

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2011-02-18
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Ormazábal Toledo, Rodrigo
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Are Electrophilicity and Electrofugality Related Concepts? A Density Functional Theory Study
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Author
  • Ormazábal Toledo, Rodrigo;
  • Campodónico, Paola R.;
  • Contreras Ramos, Renato;
Abstract
It is proposed that the electrofugality of a fragment within a molecule is determined by its group nucleophilicity. The variation of electrofugality should be tightly related to the electron releasing ability of the substituent attached to the electrofuge moiety. This contribution closes the set of relationships between philicity and fugality quantities: while nucleofugality appears related to the group electrophilicity of the leaving group, electrofugality is related to the group nucleophilicity of the permanent group.
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Artículo de publicación ISI
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Fondecyt 1070715 1100492
Identifier
URI: https://repositorio.uchile.cl/handle/2250/119373
DOI: DOI: 10.1021/ol103033j
ISSN: 1523-7060
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Organic Letters Volume: 13 Issue: 4 Pages: 822-824 Published: FEB 18 2011
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