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INFRARED ASSIGNMENT AND FORMATION MECHANISM OF TRANS-ANTI THYMINE DIMER

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1987-04-11
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Cárdenas Jirón, G. I.
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INFRARED ASSIGNMENT AND FORMATION MECHANISM OF TRANS-ANTI THYMINE DIMER
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Author
  • Cárdenas Jirón, G. I.;
  • Figueroa, K. A.;
  • Vargas C., V.;
  • Gómez Jeria, Juan;
  • Campos Vallette, Marcelo;
Abstract
Thymine dimers were obtained under ultraviolet irradiation. The major product is a trans-anti dimer linked by a cyclobutane ring. The infrared assignments and the mechanism of formation of this dimer are discussed in terms of an approximate force field and INDO data, respectively.
Patrocinador
This research is supported by a Grant from the Departamento de Investigación y Bibliotecas of the Universidad de Chile and FONDECYT proyect, contracts 310-1393. We thank SECI.for providing computer time.
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URI: https://repositorio.uchile.cl/handle/2250/119576
ISSN: 0038-7010
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SPECTROSCOPY LETTERS, 21(2), 107-125, 1988.
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