INFRARED ASSIGNMENT AND FORMATION MECHANISM OF TRANS-ANTI THYMINE DIMER
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1987-04-11Metadata
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Cárdenas Jirón, G. I.
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INFRARED ASSIGNMENT AND FORMATION MECHANISM OF TRANS-ANTI THYMINE DIMER
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Abstract
Thymine dimers were obtained under ultraviolet irradiation. The
major product is a trans-anti dimer linked by a cyclobutane ring. The
infrared assignments and the mechanism of formation of this dimer are
discussed in terms of an approximate force field and INDO data, respectively.
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This research is supported by a Grant from the Departamento
de Investigación y Bibliotecas of the Universidad de Chile and FONDECYT
proyect, contracts 310-1393. We thank SECI.for providing computer time.
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SPECTROSCOPY LETTERS, 21(2), 107-125, 1988.
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