| Author | dc.contributor.author | Squella Serrano, Juan | |
| Author | dc.contributor.author | Cassels Niven, Bruce | es_CL |
| Author | dc.contributor.author | Arata, M. | es_CL |
| Author | dc.contributor.author | Bavestrello, M. P. | es_CL |
| Author | dc.contributor.author | Núñez Vergara, Luis | es_CL |
| Admission date | dc.date.accessioned | 2012-11-15T18:02:50Z | |
| Available date | dc.date.available | 2012-11-15T18:02:50Z | |
| Publication date | dc.date.issued | 1993-03-23 | |
| Cita de ítem | dc.identifier.citation | Talanta, Vol. 40, No. 9, pp. 1379-1384, 1993 | es_CL |
| Identifier | dc.identifier.issn | 0039-9140 | |
| Identifier | dc.identifier.uri | https://repositorio.uchile.cl/handle/2250/119593 | |
| Abstract | dc.description.abstract | Four amphetamine derivatives bearing a methylenedioxy group at positions 3 and 4 of the
benzene ring and differing in their substitution at C(6) were studied by differential pulse voltammetry in
aqueous media. These experiments showed a single oxidation peak for the C(6)-H, -Br and -CI compounds,
while the C(6)-N02 analogue was not oxidized. The oxidation peak is interpreted as due to the removal
of one eleetron from the aromatic eleetrophore with formation of a radical cation stabilized by the dioxole
ring. The linear relationship between the peak current and the concentration of the derivatives is
appropriate for development of a quantitative method for their determination. pK' values were determined
using both eleetrochemical and spectrophotometric methods. | es_CL |
| Patrocinador | dc.description.sponsorship | This work was supported in part by
FONDECYT grants N" 915-89, 1110-92 and DTI Universidad
de Chile grant N° 3121-9223. | es_CL |
| Lenguage | dc.language.iso | en | es_CL |
| Publisher | dc.publisher | Pergamon Press Ltd. | es_CL |
| Título | dc.title | Electrochemical oxidation of methylenedioxy amphetamines | es_CL |
| Document type | dc.type | Artículo de revista | |
