The structure of the first supramolecular α-cyclodextrin complex with an aliphatic monofunctional carboxylic acid
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Rodríguez Llamazares, Saddys María
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The structure of the first supramolecular α-cyclodextrin complex with an aliphatic monofunctional carboxylic acid
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Abstract
The crystal structure of the supramolecular complex between α-cyclodextrin and decanoic acid was determined: The aliphatic chain of the carboxylic acid is threaded through a head-to-head dimer of two cyclodextrin residues, resulting in a 1:2 stoichiometry. Head-to-head orientation is also observed between neighboring complexes. The overall degree of hydration with 25 water molecules per supramolecular complex is remarkably high
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URI: https://repositorio.uchile.cl/handle/2250/154584
DOI: 10.1002/ejoc.200700454
ISSN: 1434193X
10990690
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Eur. J. Org. Chem.2007, 4298–4300
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