Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate
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Baggio, Ricardo
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Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate
Abstract
The new heterobimetallic complex [{LaEu(oda)3(H2O)3.-5H2O} n] (oda = -O2CCH2OCH2CO2 -) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller EuIII cation, while six adjacent outer carboxylate O atoms and three metal-bound water O atoms are bonded to the larger LaIII cation. The structure consists of a three-dimensional network with the metal centers bridged by oda carboxylate groups, with Eu⋯La separations of 6.95 (1) Å.
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URI: https://repositorio.uchile.cl/handle/2250/156861
DOI: 10.1107/S0108270197017356
ISSN: 01082701
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Acta Crystallographica Section C: Crystal Structure Communications, Volumen 54, Issue 5, 2018, Pages 591-594
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