Electrochemical behaviour of NN′-thiobisamines. Cyclic voltammetry in dimethyl sulphoxide with low water content
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González Moraga, Guillermo
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Electrochemical behaviour of NN′-thiobisamines. Cyclic voltammetry in dimethyl sulphoxide with low water content
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The electrochemical behaviour of NN′-thiobispiperidine and NN′-thiobismorpholine in dimethyl sulphoxide at low water content has been studied by cyclic voltammetry. Electro-oxidation in this medium, producing SO<inf>2</inf> at the electrode surface, parallels the process observed by adding a Brönsted acid in which acid catalysed hydrolysis generates an intermediate species which is followed by a disproportionation process.
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URI: https://repositorio.uchile.cl/handle/2250/157081
DOI: 10.1039/P29830001803
ISSN: 1472779X
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